I have search the forum and found topics related to this problem.
I check localrc file in both 32&64 version of pgi
They both have correct path with Fedora Core 4 (with compat-gcc-32-g77-3.2.3-47.fc4).
However, no matter which PGI(32 or 64) compiler(latest 6.0.4) I choose,
crtbegin.o error happend all the time.